white flour there is less than .05 of a per cent; in oatmeal and cereal products from .5 to 1 per cent, depending upon the extent to which the hulls are removed, and in vegetable foods from .1 to 1 per cent. The cellulose content of foods is included in the crude fiber of the chemist's report.
9. Starch occurs widely distributed in nature, particularly in the seeds, roots, and tubers of some plants. It is formed in the leaves of plants as a result of the joint action of chlorophyll and protoplasm, and is generally held by plant physiologists to be the first carbohydrate produced in the plant cell. Starch is composed of a number of overlapping layers separated by starch cellulose; between these layers the true starch or amylose is found. Starch from the various cereals and vegetables differs widely in mechanical structure; in wheat it is circular, in corn somewhat angular, and in parsnips exceedingly small, while potato starch granules are among the largest.[4] The nature of starch can be determined largely from its mechanical structure as studied under the microscope. It is insoluble in cold water because of the protecting action of the cellular layer, but on being heated it undergoes both mechanical and chemical changes; the grains are partially ruptured by pressure due to the conversion into steam of the moisture held mechanically. The cooking of foods is beneficial from a mechanical point of view, as it results in partial disintegration of the starch masses, changing the structure so that the starch is more readily acted upon by the ferments of the digestive tract. At a temperature of about 120° C. starch begins to undergo chemical change, resulting in the rearrangement of the atoms in the molecule with the production of dextrine and soluble carbohydrates. Dextrine is formed on the crust of bread, or whenever potatoes or starchy foods are browned. At a still higher temperature starch is decomposed, with the liberation of water and production of compounds of higher carbon content. When heated in contact with water, it undergoes hydration changes; gelatinous-like products are formed, which are finally converted into a soluble condition. In cooking cereals, the hydration of the starch is one of the main physical and chemical changes that takes place, and it simply results in converting the material into such a form that other chemical changes may more readily occur. Before starch becomes dextrose, hydration is necessary. If this is accomplished by cooking, it saves the body just so much energy in digestion. Many foods owe their value largely to the starch. In cereals it is found to the extent of 72 to 76 per cent; in rice and potatoes in still larger amounts; and it is the chief constituent of many vegetables. When starch is digested, it is first changed to a soluble form and then gradually undergoes oxidation, resulting in the production of heat and energy, the same products--carbon dioxide and water--being formed as when starch is burned. Starch is a valuable heat-producing nutrient; a pound yields 1860 calories. See Chapter XV.
10. Sugar.--Sugars are widely distributed in nature, being found principally in the juices of the sugar cane, sugar beet, and sugar maple. They are divided into two large classes: the sucrose group and the dextrose group, the latter being produced from sucrose, starch, and other carbohydrates by inversion and allied chemical changes. Because of the importance of sugar in the dietary, Chapter V is devoted to the subject.
11. Pectose Substances are jelly-like bodies found in fruits and vegetables. They are closely related in chemical composition to the carbohydrates, into which form they are changed during digestion; and in nutrition they serve practically the same function. In the early stages of growth the pectin bodies are combined with organic acids, forming insoluble compounds, as the pectin in green apples. During the ripening of fruit and the cooking of vegetables, the pectin is changed to a more soluble and digestible condition. In food analysis, the pectin is usually included with the carbohydrates.
12. Nitrogen-free-extract.--In discussing the composition of foods, the carbohydrates other then cellulose, as starch, sugar, and pectin, are grouped under the name of nitrogen-free-extract. Methods of chemical analysis have not yet been sufficiently perfected to enable accurate and rapid determination to be made of all these individual carbohydrates, and hence they are grouped together as nitrogen-free-extract. As the name indicates, they are compounds which contain no nitrogen, and are extractives in the sense that they are soluble in dilute acid and alkaline solutions. The nitrogen-free-extract is determined indirectly, that is, by the method of difference. All the other constituents of a food, as water, ash, crude fiber (cellulose), crude protein, and ether extract, are determined; the total is subtracted from 100, and the difference is nitrogen-free-extract. In studying the nutritive
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