Scientific American, Volume XLIII., No. 25, December 18, 1880 | Page 5

a wave in the rope, so will every vibration of a part of the molecule start a wave in the ether. Now we have several methods for measuring the wave lengths in ether, and we also know the velocity of movement. Let v = velocity, l = wave length, and n = number of vibrations per second, then n = v/l, and by calculation the value of n varies within wide limits, say from 1 �� 10^{14} to 20 �� 10^{14}. But all vibrating bodies are capable of vibrating in several periods, the longest period being called the fundamental, and the remainder, which stand in some simple ratios to the fundamental, are called harmonics. Each of these will give to the ether its own particular vibratory movement, so that a single molecule may be constantly giving out rays of many wave lengths precisely as a sounding bell gives out sounds of various pitches at one and the same time.
Again, when these undulations in the ether fall upon other molecules the latter may reflect them away or they may absorb them, in which case the absorbing molecules are themselves made to vibrate with increased amplitude, and we say they have been heated. Some molecules, such as carbon, appear to be capable of stopping undulations of all wave lengths and to be heated by them; others are only affected by undulations of particular wave lengths, or of wave lengths between special limits. In this case it is a species of sympathetic vibration. The distinction between the molecular vibrations, and the undulations in ether that result from them, must be kept in mind, as must also the effect of the undulations that fall upon other molecules. To one the name heat is applied, to the other the name of radiant energy is given; and it matters not whether the undulations be long or short, the same molecule may give out both.
Now let a prism be placed in the path of such rays of different wave length from a single molecule, and what is called the dispersive action of the prism will separate the rays in the order of their wave lengths, the longer waves being less refracted than the shorter ones; but the energy of any one of these will depend upon the amplitude of undulation, which in turn will depend upon the amplitude of vibration of the part of the molecule that originated it, but in general the longer waves have greater amplitude, though not necessarily so. Consequently, if a thermopile be so placed as to receive these various rays, and their energy be measured by its absorption on the face of the pile, each one would be found to heat it, the longer waves more than the shorter ones, simply because the amplitude is greater, but for no other reason, for it is possible, and in certain cases is the fact, that a short wave has as much or more energy than a longer one. If the eye should take the place of the thermopile it would be found that some of these rays did not affect it at all, while some would produce the sensation of light. This would be the case with any waves having a wave length between the limits of, say, 1-37,000 of an inch and 1-60,000 of an inch; any shorter waves will not produce the sensation of light. If instead of the eye a piece of paper washed in a solution of the chloride of silver should be placed where the dispersed rays should fall upon it, it would be found that only the shorter waves would affect it at all, and among these shorter ones would be some of those rays which the eye could not perceive at all.
It was formerly inferred from these facts that the heat rays, the light rays, and the chemical rays were different in quality; and some of the late books treating upon this very subject represent a solar spectrum as being made up of a heat spectrum, a light spectrum, and an actinic or chemical spectrum, and the idea has often been made to do duty as an analogy in trinitarian theology; nevertheless it is utterly wrong and misleading. There is no such thing as an actinic spectrum; that is, there are no such rays as special chemical rays; any given ray will do chemical work if it falls upon the proper kind of matter. For instance, while it is true that for such salts of silver as the chloride, the bromide, etc., the shorter waves are most efficient; by employing salts of iron one may get photographic effects with wave lengths much too long for any eye to perceive. Capt. Abney has photographed the whole solar spectrum from one end to the other, which is sufficient evidence