Fields Chromatography | Page 9

palette than to a supply of well-burnt and levigated enamel pigments. But though such colours for the most part stand well when fluxed on glass, or in the glazing of enamel, they are nearly, without exception, subject to the most serious changes when ground to the degree of fineness necessary to their application as pigments, and become liable to all the chemical changes and affinities of the substances which compose them. These remarks even apply in a measure to native products, such as coloured earths and metallic ores.
Others have not unreasonably supposed that when pigments are locked up in varnishes and oils, they are safe from all possibility of change. The assumption would be more warranted if we had an impenetrable varnish--and even that would not resist the action of light, however well it might exclude the influence of air and moisture. But, in fact, varnishes and oils themselves yield to changes of temperature, to the action of a humid atmosphere, and to other influences: their protection of colour from change is therefore far from perfect.
Want of attention to the unceasing mutability of all chemical substances, as well as to their reciprocal actions, has occasioned those changes of colour to be ascribed to fugitiveness of the pigment, which belong to the affinities of other substances with which it has been improperly mixed and applied. It is thus that the best pigments have suffered in reputation under the injudicious processes of the painter; although, owing to a desultory practice, the effects and results have not been uniform. If a colour be not extremely permanent, dilution will render it in some measure more weak and fugitive; and this occurs in several ways--by a too free use of the vehicle; by complex mixture in the formation of tints; by distribution, in glazing or lackering, of colours upon the lights downward, or scumbling colours upon the shades upward; or by a mixed mode very common among the Venetian painters, in which opaque pigments are combined, as umber and lake.
The fugitive colours do less injury in the shadows than in the lights of a picture, because they are employed pure, and in greater body in shadows, and are therefore less liable to decay by the action of light, and by mixture. Through partially fading, moreover, they balance any tendency to darken, to which the dead colouring of earthy and metallic pigments is disposed.
The foregoing circumstances, added to the variableness of pigments by nature, preparation, and sophistication, have often rendered their effects equivocal, and their powers questionable. These considerations enforce the expediency of using colours as pure and free from unnecessary mixture as possible; for simplicity of composition and management is equally a maxim of good mechanism, good chemistry, and good colouring. Accordingly, in respect to the latter, Sir Joshua Reynolds remarks, "Two colours mixed together will not preserve the brightness of either of them single, nor will three be as bright as two: of this observation, simple as it is, an artist who wishes to colour bright will know the value."
There prevail, notwithstanding, two principles of practice on the palette, opposed to each other--the one, simple; the other, multiple. The first is that of having as few pigments as possible; and consists, when carried to the extreme, in employing the three primary colours only. The second is that of having a number of pigments; and consists, also when carried to the extreme, of employing as many, if possible, as there are hues and shades of colour.
On the former plan, every tint requires to be compounded; on the latter, one pigment supplies the place of two or more. Now, the more pigments are mixed, the more they are deteriorated in colour, attenuated, and chemically set at variance. Original pigments, that is, such as are not made up of two or more colours, are purer in hue and generally more durable than those compounded. Hence pure intermediate tints in single, permanent, original pigments, are to be preferred to pigments compounded, often to the dilution and injury of their colours. Cadmium Orange, for instance, which is naturally an orange pigment and not composed of red and yellow, is superior to many mixtures of those colours in a chemical sense, and to all such mixtures in an artistic sense. At the same time, it is quite possible for the artist to multiply his pigments unnecessarily. Colours are sometimes brought out under new names which have no claim to be regarded as new colours, being, indeed, mere mixtures. Compound pigments like these may most frequently be dispensed with, in favour of hues and tints composed extemporaneously of original colours upon the palette.
It may be inferred from the foregoing that, between the modes of employing as few pigments as possible, and of having as many as there are hues and shades